Photo-Fenton processes have been widely studied in wastewater treatment. In this research, the degradation of bisphenol A (BPA) was carried out in a new heterogeneous photo-Fenton process. The ethylenediamine-N,N'-disuccinic acid (EDDS) was used as chelating agent in this system with two different kinds of commercially available nanosized hematite (30&nbsp;nm and 80&nbsp;nm) addition. The results showed that the present of EDDS could enhance the degradation efficiency. And can be concluded that the degradation efficiency is better in the system with 30&nbsp;nm hematite. The TEM, XRD, and specific surface area were conducted to understand the different characteristics of the two size hematite. The adsorption experiments of BPA and EDDS on hematite proved that there was little adsorption of BPA while the EDDS was adsorbed much more on hematite, which has confirmed Fe(III) and EDDS can form Fe(III)-EDDS complex. The effects of different parameters including hematite loading, H2O2, and EDDS concentrations on the degradation process were investigated. According to the results, the optimum condition for BPA degradation using 30&nbsp;nm (0.8&nbsp;g&nbsp;L-1 hematite, 0.1&nbsp;mmol&nbsp;L-1 H2O2, and 1.2&nbsp;mmol&nbsp;L-1 EDDS) and 80&nbsp;nm (0.6&nbsp;g&nbsp;L-1 hematite, 0.05&nbsp;mmol&nbsp;L-1 H2O2, and 1.2&nbsp;mmol&nbsp;L-1 EDDS) hematite were selected. It was confirmed that the ?OH plays an important role in the oxidation process through attacking the BPA molecule and produce hydroxyl addition derivative. In addition, O2 can react with electron (e-) and holes (h+) produced by iron oxide under UV irradiation to create 1O2, which could work as potential reactive species to oxidize BPA.The diesel vehicle emissions regarding particles have become a problem due to human health adversely. Especially ultrafine particles (diameter???100&nbsp;nm) can deeply penetrate the human body leading to cell deformation. Investigation of the diesel ultrafine particle exposure to the cell deformation has become a challenge to build up understanding the impacts of ultrafine particles on human health. Moreover, the relationship between high exposure to diesel ultrafine particles and the deformation of the rat's tubular epithelial cells is not clear. In this study, we investigated the impact of the diesel ultrafine particle exposure to the rat's tubular cells. Three diesel busses were used as the sources of the particles, while 50 rats were used as the experimental animals. The diesel emission was filtered using an N95 particulate filter and a suction pump. The rats were exposed to the diesel ultrafine particle emission for 100&nbsp;s with three different concentrations C1, C2, and C3 for eight consecutive days. All rats were sacrificed on the day after exposures to examine the histological images. The results showed that the deformation level of the tubular epithelial cells was positively associated with the concentration of the ultrafine particles.The installation of district heating (DH) systems constitutes an advantage from the energetic, climate, and air quality aspects. However, the configuration and operational features of a DH system affect significantly its environmental performance. The objective of the present study is the energetic and environmental assessment of DH networks that present differences in size and operating configurations, to define relevant environmental performance indicators. Three case studies in Italy are analyzed, following a methodology based on the impact pathway approach that was presented by the authors in previous studies. Case studies are evaluated in terms of total emission, pollutant concentration (NOx, CO, PM), and health damage external costs. Results show that lower pollutant emissions are associated with the installation of a DH system compared to autonomous residential boilers. Air quality is also improved and health externalities are reduced. The results of CO2 savings are differentiated depending on the efficiency and emission factors of the systems. An inter-comparison of different cases is then presented, based on the elaboration of specific indicators of environmental and health impacts. This section shows that, besides the size of the DH system, other factors, such as population density and geographical distribution of pollutants concentration, are important. Among the indicators considered, those based on health externalities provide more complete and comparable information on the final impact of the alternative solutions on the exposed population. Their application seems thus promising for the evaluation of alternative planning strategies for DH systems.Anthropogenic effluent dissolved organic matter (DOM) plays an important role in coastal zone pollution. The objectives of the present study were to characterize the fluorescence signal of anthropogenic effluent DOM from wastewater treatment plant and to evaluate the effect of solar irradiation on the fluorescence signal in the coastal zone. Solar irradiation experiments were conducted to evaluate the effect photochemical degradation using excitation-emission matrix (EEM) method combined with parallel factor analysis (PARAFAC). Results showed high fluorescence of DOM before irradiation and the intensity tends to decrease after 4th and 15th day of irradiation. Rapid photochemical degradation of humic-like fluorophores and appearance of a post-irradiance dominant anthropogenic effluent DOM fluorophores were also observed after irradiation. https://www.selleckchem.com/products/alkbh5-inhibitor-2.html Our experiments showed a sharp reduction in fluorescence intensity which occurred after 4th day of solar irradiation and the fluorescence signal did not disappeared after 15t degradation with increase of fSW and fRW and the predominance of the residual fluorescence coming from fWW which is the content fraction of anthropogenic effluent DOM because AWWi,0 was 100 times less sensitive to photobleaching. A suitable model for predicting the fluorescence EEMs as a function of mixing composition was developed.Metal oxide nanoparticles (NPs) have different industrial applications so it is unavoidable that NPs products could find their way into aquatic habitats. Therefore, toxic NPs must be treated sufficiently to reach the standard values before their discharge into the aquatic ecosystems. Our study aimed to investigate the adsorptive capacity of rice husk to iron and aluminum oxides from water and reducing their potential toxic effects. Fish were classified into eight groups for 7&nbsp;days Fe2O3 NPs (10&nbsp;mg/l)-exposed group; Al2O3 NPs (10&nbsp;mg/l)-exposed group; combined group (same concentrations of Fe2O3 and Al2O3NPs), and control group (dechlorinated water). The other four groups were the same as the above groups but with 50&nbsp;mg/l rice husk in each group. Compared with control groups, our results showed a significant (p? less then ?0.05) increase in plasma total proteins, globulin, glucose, liver enzymes, and kidney function biomarkers (creatinine and uric acid). While the recorded albumin and total lipids were significantly decreased.